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Registro Completo |
Biblioteca(s): |
Embrapa Instrumentação. |
Data corrente: |
20/09/2021 |
Data da última atualização: |
10/06/2022 |
Tipo da produção científica: |
Artigo em Periódico Indexado |
Autoria: |
MORAIS, C. P. de; NICOLODELLI, G.; FOSCHINI, M. M.; SILVA, K. S. G. da; MAUAD, F. F.; MOUNIER, S.; MILORI, D. M. B. P. |
Afiliação: |
MILENE CORSO MITSUYUKI, CNPDIA; DEBORA MARCONDES BASTOS PEREIRA, CNPDIA. |
Título: |
Total phosphorus determination in eutrophic tropical river sediments by laser-induced breakdown spectroscopy techniques. |
Ano de publicação: |
2021 |
Fonte/Imprenta: |
Analytical Methods, v. 13, 2021. |
Páginas: |
77 - 83 |
ISSN: |
1759-9660 |
DOI: |
10.1039/d0ay02008g |
Idioma: |
Inglês |
Conteúdo: |
Total phosphorus (TP) in sediments is an important chemical variable in the study of the extent of eutrophication in water bodies. Two methods, based on single pulse (SP) and double pulse (DP) laserinduced breakdown spectroscopy (LIBS), were developed for determining TP in the sediment cores of Brazilian rivers upstream from the Barra Bonita reservoir. TP concentration in the sediments was determined by inductively coupled plasma optical emission spectrometry (ICP OES) on digested samples. Besides, a LIBS system operating in SP and DP modes was used to develop methods for TP quantification in sediment pellets. In LIBS, the most appropriate wavelength to measure P was 214.91 nm. The calibration curves showed correlation coefficients of 0.93 and 0.92 and limits of detection of 709 mg kg#1;1 and 349 mg kg#1;1 for SP and DP LIBS, respectively. The two proposed methods were validated and the average percentage errors were 14% and 10% for SP and DP LIBS, respectively. The ICP OES and SP and DP LIBS data showed that the most superficial layers of the Piracicaba River, all the sedimentary layers of the Tiete River, and the con ˆ fluence region present a high concentration of TP, according to the Brazilian sediment quality criterion. In conclusion, SP and DP LIBS were confirmed as promising alternative tools to traditional analytical methods for monitoring the TP content in the sediments that come from different hydrographic units. The proposed method using DP LIBS proved more sensitive than SP LIBS, but the SP LIBS method demonstrated enough precision for determining TP in eutrophic river sediments. MenosTotal phosphorus (TP) in sediments is an important chemical variable in the study of the extent of eutrophication in water bodies. Two methods, based on single pulse (SP) and double pulse (DP) laserinduced breakdown spectroscopy (LIBS), were developed for determining TP in the sediment cores of Brazilian rivers upstream from the Barra Bonita reservoir. TP concentration in the sediments was determined by inductively coupled plasma optical emission spectrometry (ICP OES) on digested samples. Besides, a LIBS system operating in SP and DP modes was used to develop methods for TP quantification in sediment pellets. In LIBS, the most appropriate wavelength to measure P was 214.91 nm. The calibration curves showed correlation coefficients of 0.93 and 0.92 and limits of detection of 709 mg kg#1;1 and 349 mg kg#1;1 for SP and DP LIBS, respectively. The two proposed methods were validated and the average percentage errors were 14% and 10% for SP and DP LIBS, respectively. The ICP OES and SP and DP LIBS data showed that the most superficial layers of the Piracicaba River, all the sedimentary layers of the Tiete River, and the con ˆ fluence region present a high concentration of TP, according to the Brazilian sediment quality criterion. In conclusion, SP and DP LIBS were confirmed as promising alternative tools to traditional analytical methods for monitoring the TP content in the sediments that come from different hydrographic units. The proposed method using DP LIBS proved more sensit... Mostrar Tudo |
Palavras-Chave: |
Chemical variable; Piracicaba River; SP and DP LIBS. |
Categoria do assunto: |
-- |
Marc: |
LEADER 02401naa a2200265 a 4500 001 2134588 005 2022-06-10 008 2021 bl uuuu u00u1 u #d 022 $a1759-9660 024 7 $a10.1039/d0ay02008g$2DOI 100 1 $aMORAIS, C. P. de 245 $aTotal phosphorus determination in eutrophic tropical river sediments by laser-induced breakdown spectroscopy techniques.$h[electronic resource] 260 $c2021 300 $a77 - 83 520 $aTotal phosphorus (TP) in sediments is an important chemical variable in the study of the extent of eutrophication in water bodies. Two methods, based on single pulse (SP) and double pulse (DP) laserinduced breakdown spectroscopy (LIBS), were developed for determining TP in the sediment cores of Brazilian rivers upstream from the Barra Bonita reservoir. TP concentration in the sediments was determined by inductively coupled plasma optical emission spectrometry (ICP OES) on digested samples. Besides, a LIBS system operating in SP and DP modes was used to develop methods for TP quantification in sediment pellets. In LIBS, the most appropriate wavelength to measure P was 214.91 nm. The calibration curves showed correlation coefficients of 0.93 and 0.92 and limits of detection of 709 mg kg#1;1 and 349 mg kg#1;1 for SP and DP LIBS, respectively. The two proposed methods were validated and the average percentage errors were 14% and 10% for SP and DP LIBS, respectively. The ICP OES and SP and DP LIBS data showed that the most superficial layers of the Piracicaba River, all the sedimentary layers of the Tiete River, and the con ˆ fluence region present a high concentration of TP, according to the Brazilian sediment quality criterion. In conclusion, SP and DP LIBS were confirmed as promising alternative tools to traditional analytical methods for monitoring the TP content in the sediments that come from different hydrographic units. The proposed method using DP LIBS proved more sensitive than SP LIBS, but the SP LIBS method demonstrated enough precision for determining TP in eutrophic river sediments. 653 $aChemical variable 653 $aPiracicaba River 653 $aSP and DP LIBS 700 1 $aNICOLODELLI, G. 700 1 $aFOSCHINI, M. M. 700 1 $aSILVA, K. S. G. da 700 1 $aMAUAD, F. F. 700 1 $aMOUNIER, S. 700 1 $aMILORI, D. M. B. P. 773 $tAnalytical Methods$gv. 13, 2021.
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Embrapa Instrumentação (CNPDIA) |
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Registro Completo
Biblioteca(s): |
Embrapa Acre. |
Data corrente: |
11/06/2002 |
Data da última atualização: |
18/05/2023 |
Tipo da produção científica: |
Documentos |
Autoria: |
FIGUEIREDO, E. O. |
Afiliação: |
EVANDRO ORFANO FIGUEIREDO, CPAF-AC. |
Título: |
Reflorestamento com teca (Tectona grandis L. F.) no estado do Acre. |
Ano de publicação: |
2001 |
Fonte/Imprenta: |
Rio Branco, AC: Embrapa Acre, 2001. |
Páginas: |
28 p. |
Série: |
(Embrapa Acre. Documentos, 65). |
ISSN: |
0104-9046 |
Idioma: |
Português |
Conteúdo: |
Introdução; Aspectos ambientais; Desempenho da teca no Estado do Acre; Principais critérios para seleção de áreas; Cuidados para instalação e condução do reflorestamento; Conclusão. |
Palavras-Chave: |
Acre; Amazon; Amazonia Occidental; Amazônia Ocidental; Amazônia: Brasil; Brasil; Densidade do plantio; Desempenho; Desempenho silvicultural; Desempenho sivicultural; Environmental impact assessment; F; Forest; Plant population; População de plantas; Reflorestation; Reforestación; Spacing; Species; Teak; Tectona grandis L; Timber trees; Western Amazon. |
Thesagro: |
Árvore Angiosperma; Clima; Densidade de Plantio; Espécie; Floresta; Impacto Ambiental; Planta Produtora de Madeira; Plantio; Reflorestamento; Silvicultura; Teca; Tectona Grandis. |
Thesaurus NAL: |
Amazonia; Brazil; climate; deforestation; environmental impact; planting; reforestation; Tectona; trees. |
Categoria do assunto: |
-- K Ciência Florestal e Produtos de Origem Vegetal |
URL: |
https://ainfo.cnptia.embrapa.br/digital/bitstream/item/117320/1/4495.pdf
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Marc: |
LEADER 01901nam a2200673 a 4500 001 1495886 005 2023-05-18 008 2001 bl uuuu u0uu1 u #d 022 $a0104-9046 100 1 $aFIGUEIREDO, E. O. 245 $aReflorestamento com teca (Tectona grandis L. F.) no estado do Acre. 260 $aRio Branco, AC: Embrapa Acre$c2001 300 $a28 p. 490 $a(Embrapa Acre. Documentos, 65). 520 $aIntrodução; Aspectos ambientais; Desempenho da teca no Estado do Acre; Principais critérios para seleção de áreas; Cuidados para instalação e condução do reflorestamento; Conclusão. 650 $aAmazonia 650 $aBrazil 650 $aclimate 650 $adeforestation 650 $aenvironmental impact 650 $aplanting 650 $areforestation 650 $aTectona 650 $atrees 650 $aÁrvore Angiosperma 650 $aClima 650 $aDensidade de Plantio 650 $aEspécie 650 $aFloresta 650 $aImpacto Ambiental 650 $aPlanta Produtora de Madeira 650 $aPlantio 650 $aReflorestamento 650 $aSilvicultura 650 $aTeca 650 $aTectona Grandis 653 $aAcre 653 $aAmazon 653 $aAmazonia Occidental 653 $aAmazônia Ocidental 653 $aAmazônia: Brasil 653 $aBrasil 653 $aDensidade do plantio 653 $aDesempenho 653 $aDesempenho silvicultural 653 $aDesempenho sivicultural 653 $aEnvironmental impact assessment 653 $aF 653 $aForest 653 $aPlant population 653 $aPopulação de plantas 653 $aReflorestation 653 $aReforestación 653 $aSpacing 653 $aSpecies 653 $aTeak 653 $aTectona grandis L 653 $aTimber trees 653 $aWestern Amazon
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