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Registro Completo |
Biblioteca(s): |
Embrapa Agroindústria de Alimentos. |
Data corrente: |
28/05/2019 |
Data da última atualização: |
07/02/2020 |
Tipo da produção científica: |
Resumo em Anais de Congresso |
Autoria: |
BRILHANTE, N. S.; BIZZO, H. R.; FARIA-MACHADO, A. F. de; SANTOS, M. C. da S.; GAMA, P. E. |
Afiliação: |
Nathália Simon Brilhante; HUMBERTO RIBEIRO BIZZO, CTAA; ADELIA FERREIRA DE FARIA MACHADO, CTAA; MARCELLY CRISTINA DA SILVA SANTOS, CTAA; PAOLA ERVATTI GAMA, CTAA. |
Título: |
Method development for the analysis of volatile compounds in olive oil. |
Ano de publicação: |
2019 |
Fonte/Imprenta: |
In: CONGRESSO DE ÓLEOS E GORDURAS, 4., INTERNATIONAL MEETEING ON FATS AND OILS. Campinas, 2019. Anais... Campinas: SBOG, p. 12. |
Idioma: |
Inglês |
Notas: |
De 15 a 16 maio 2019. Trabalhos apresentados de forma oral. |
Conteúdo: |
Olive oil consists mainly of triglycerides, in about 97 to 99% by weight. The minor compounds are a complex mixture of polar, apolar and amphiphilic substances, such as tocopherols, phenolic compounds, sterols, chlorophyll, carotenoids, terpene acids, monoglycerides and diglycerides, free fatty acids and volatile compounds. These volatiles are the compounds directly responsible for the aroma of the oil. Extra virgin olive oil has a complex aroma with more than 100 volatile compounds identified, among aldehydes, alcohols, esters, hydrocarbons, ketones and furans. The objective of this study was to develop an analytical method for volatile compounds in olive oils using solid-phase microextraction (SPME), gas chromatography coupled to mass spectrometry (GC-MS) and gas chromatography with flame ionization detection (GC-FID). For the SPME, different parameters like flask size (4, 10 and 20 mL), sampling temperatures (40 and 60 °C), headspace conditioning (10 and 60 min) and fiber exposure times (15 and 40 min) were tested. For GC analyses two different internal standards, methyl octanoate and tetradecane, were tested, as well as sub-ambient oven temperatures with liquid nitrogen. A 1 g of sample and a divinylbenzene/carboxen/polydimethylsiloxane (DVB/CAR/PMDS) fiber were used in all the tests. Analytical curves from the FID data were constructed for linearity evaluation, whereas internal standard was used for quantification ofcompounds such as 3-hexenol, 2-hexanal and limonene. Identification was performed based on mass spectra, co-injection of standards and retention indices data. The best conditions for SPME analysis were sample temperature of 40 °C, 10 min of headspace conditioning and fiber exposure for 40 min, in a 4 mL flask. For the chromatographic analyzes, tetradecane was chosen as the internal standard. Oven temperature program with cryofocusing led to a much better separation and, therefore, better quantitation and identification of the morevolatile compounds. MenosOlive oil consists mainly of triglycerides, in about 97 to 99% by weight. The minor compounds are a complex mixture of polar, apolar and amphiphilic substances, such as tocopherols, phenolic compounds, sterols, chlorophyll, carotenoids, terpene acids, monoglycerides and diglycerides, free fatty acids and volatile compounds. These volatiles are the compounds directly responsible for the aroma of the oil. Extra virgin olive oil has a complex aroma with more than 100 volatile compounds identified, among aldehydes, alcohols, esters, hydrocarbons, ketones and furans. The objective of this study was to develop an analytical method for volatile compounds in olive oils using solid-phase microextraction (SPME), gas chromatography coupled to mass spectrometry (GC-MS) and gas chromatography with flame ionization detection (GC-FID). For the SPME, different parameters like flask size (4, 10 and 20 mL), sampling temperatures (40 and 60 °C), headspace conditioning (10 and 60 min) and fiber exposure times (15 and 40 min) were tested. For GC analyses two different internal standards, methyl octanoate and tetradecane, were tested, as well as sub-ambient oven temperatures with liquid nitrogen. A 1 g of sample and a divinylbenzene/carboxen/polydimethylsiloxane (DVB/CAR/PMDS) fiber were used in all the tests. Analytical curves from the FID data were constructed for linearity evaluation, whereas internal standard was used for quantification ofcompounds such as 3-hexenol, 2-hexanal and limonene. I... Mostrar Tudo |
Palavras-Chave: |
GC-FID; GC-MS; SPME. |
Thesaurus Nal: |
Olive oil; Volatile compounds. |
Categoria do assunto: |
-- |
URL: |
https://ainfo.cnptia.embrapa.br/digital/bitstream/item/197804/1/resumo-4COG-p.12.pdf
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Marc: |
LEADER 02772nam a2200229 a 4500 001 2109353 005 2020-02-07 008 2019 bl uuuu u00u1 u #d 100 1 $aBRILHANTE, N. S. 245 $aMethod development for the analysis of volatile compounds in olive oil.$h[electronic resource] 260 $aIn: CONGRESSO DE ÓLEOS E GORDURAS, 4., INTERNATIONAL MEETEING ON FATS AND OILS. Campinas, 2019. Anais... Campinas: SBOG, p. 12.$c2019 500 $aDe 15 a 16 maio 2019. Trabalhos apresentados de forma oral. 520 $aOlive oil consists mainly of triglycerides, in about 97 to 99% by weight. The minor compounds are a complex mixture of polar, apolar and amphiphilic substances, such as tocopherols, phenolic compounds, sterols, chlorophyll, carotenoids, terpene acids, monoglycerides and diglycerides, free fatty acids and volatile compounds. These volatiles are the compounds directly responsible for the aroma of the oil. Extra virgin olive oil has a complex aroma with more than 100 volatile compounds identified, among aldehydes, alcohols, esters, hydrocarbons, ketones and furans. The objective of this study was to develop an analytical method for volatile compounds in olive oils using solid-phase microextraction (SPME), gas chromatography coupled to mass spectrometry (GC-MS) and gas chromatography with flame ionization detection (GC-FID). For the SPME, different parameters like flask size (4, 10 and 20 mL), sampling temperatures (40 and 60 °C), headspace conditioning (10 and 60 min) and fiber exposure times (15 and 40 min) were tested. For GC analyses two different internal standards, methyl octanoate and tetradecane, were tested, as well as sub-ambient oven temperatures with liquid nitrogen. A 1 g of sample and a divinylbenzene/carboxen/polydimethylsiloxane (DVB/CAR/PMDS) fiber were used in all the tests. Analytical curves from the FID data were constructed for linearity evaluation, whereas internal standard was used for quantification ofcompounds such as 3-hexenol, 2-hexanal and limonene. Identification was performed based on mass spectra, co-injection of standards and retention indices data. The best conditions for SPME analysis were sample temperature of 40 °C, 10 min of headspace conditioning and fiber exposure for 40 min, in a 4 mL flask. For the chromatographic analyzes, tetradecane was chosen as the internal standard. Oven temperature program with cryofocusing led to a much better separation and, therefore, better quantitation and identification of the morevolatile compounds. 650 $aOlive oil 650 $aVolatile compounds 653 $aGC-FID 653 $aGC-MS 653 $aSPME 700 1 $aBIZZO, H. R. 700 1 $aFARIA-MACHADO, A. F. de 700 1 $aSANTOS, M. C. da S. 700 1 $aGAMA, P. E.
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Registro original: |
Embrapa Agroindústria de Alimentos (CTAA) |
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Registros recuperados : 35 | |
4. | | BRILHANTE, N, S.; FARIA-MACHADO, A. F. de; ANTONIASSI, R.; GAMA, P. E.; BIZZO, H. R. Monitoring the Profile of Volatile Compounds During the Storage of Extra Virgin Olive Oils Produced in Brazil from the Koroneiki Variety Using the HS-SPME Technique. Food analytical methods, v. 15, n. 6, p. 1508-1520, 2022.Tipo: Artigo em Periódico Indexado | Circulação/Nível: A - 2 |
Biblioteca(s): Embrapa Agroindústria de Alimentos. |
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7. | | DIDONET, A. A.; ANTONIASSI, R.; BACK, G. R; FARIA-MACHADO, A. F. de; WILHELM, A. E.; FERRAZ, I. D. K. Characterization of Amount and Quality of Tucuman Kernel Oil as a Potential Biomass. Journal of the American Oil Chemists' Society, v. 97, n. 6, p. 955-962, 2020.Tipo: Artigo em Periódico Indexado | Circulação/Nível: A - 2 |
Biblioteca(s): Embrapa Agroindústria de Alimentos. |
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10. | | BIZZO, H. R.; ANTONIASSI, R.; FARIA-MACHADO, A. F.; CONCEIÇÃO, L. D. H. C. S.; JUNQUEIRA, N. T. V. Separation of isomers of trienoic conjugated fatty acids by multidimensional gas chromatography. In: INTERNATIONAL SYMPOSIUM ON CAPILLARY CHROMATOGRAPHY, 36.; GCxGC SYMPOSIUM, 9., 2012, Riva del Garda. Abstract book. Messina: Chromaleont, 2012. p. 284.Tipo: Resumo em Anais de Congresso |
Biblioteca(s): Embrapa Agroindústria de Alimentos. |
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12. | | FARIA-MACHADO, A. F.; ANTONIASSI, R.; BIZZO, H. R.; DAMASCENO JUNIOR, P. C.; FREITAS, S. C.; DONNAGEMA, G. K. Fatty acid profile and chemical composition of seeds from Jatropha curcas during fruit ripening. In: AOCS ANNUAL MEETING & EXPO, 103., 2012, Long Beach. Abstracts. Urbana: AOCS, 2012.Tipo: Resumo em Anais de Congresso |
Biblioteca(s): Embrapa Agroindústria de Alimentos. |
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13. | | PIRES, J. M. F.; BACK, G. R.; FARIA-MACHADO, A. F.; BIZZO, H. R.; ANTONIASSI, R.; LAVIOLA, B. Conteúdo de éster de forbol vs. produção de grãos de pinhão-manso. In: CONGRESSO DA REDE BRASILEIRA DE TECNOLOGIA DE BIODIESEL, 5.; CONGRESSO BRASILEIRO DE PLANTAS OLEAGINOSAS, ÓLEOS, GORDURAS E BIODIESEL, 8., 2012, Salvador. Biodiesel, inovação e desenvolvimento regional: anais, trabalhos científicos. Lavras: UFLA, 2012. v. 2, p. 803-804.Tipo: Artigo em Anais de Congresso |
Biblioteca(s): Embrapa Agroindústria de Alimentos. |
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14. | | WILHELM, A. E.; ANTONIASSI, R.; FARIA-MACHADO, A. F.; BIZZO, H. R.; REIS, S. L. R.; CENCI, S. A. Diferentes taxas de alimentação de prensa do tipo expeller na eficiência de extração e na qualidade do óleo de semente de maracujá. Ciência Rural, Santa Maria, v. 44, n. 7, p. 1312-1318, jul. 2014. Different screw press feed rates on extraction efficiency and quality of passion fruit seed oil.Tipo: Artigo em Periódico Indexado | Circulação/Nível: A - 2 |
Biblioteca(s): Embrapa Agroindústria de Alimentos. |
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15. | | PIRES, J. M. F.; FRAUCHES, C.; SOUZA, R. S. C.; FARIA-MACHADO, A. F.; MENDONCA, S.; ANTONIASSI, R. Éster de forbol em sementes e tortas de pinhão manso. In: REUNIÃO ANUAL DA SOCIEDADE BRASILEIRA DE QUÍMICA, 34., 2011, Florianópolis. Química para um mundo melhor. São Paulo: SBQ, 2011. 1 CD-ROM.Tipo: Resumo em Anais de Congresso |
Biblioteca(s): Embrapa Agroindústria de Alimentos. |
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20. | | FREITAS, S. C. de; ANTONIASSI, R.; SIMAS, E. S.; WILHELM, A. E.; SILVA, R. P. D. da; FARIA-MACHADO, A. F. de; LAVIOLA, B. G. Composição em ácidos graxos e presença de metais e fosfolipídios em óleo de genótipos de pinhão manso. In: CONGRESSO DA REDE BRASILEIRA DE TECNOLOGIA DE BIODIESEL, 6.; CONGRESSO BRASILEIRO DE PLANTAS OLEAGINOSAS, ÓLEOS, GORDURAS E BIODIESEL, 9., 2016, Natal, RN. Biodiesel: 10 anos de pesquisa, desenvolvimento e inovação no Brasil: anais. Lavras: UFLA, 2016. Não paginado.Biblioteca(s): Embrapa Agroindústria de Alimentos. |
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Registros recuperados : 35 | |
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