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Registro Completo |
Biblioteca(s): |
Embrapa Florestas. |
Data corrente: |
04/03/2021 |
Data da última atualização: |
12/04/2021 |
Tipo da produção científica: |
Artigo em Periódico Indexado |
Autoria: |
ARTNER, M. A.; CADEMARTORI, P. H. G. de; AVELINO, F.; LEMONACO, D.; MAGALHAES, W. L. E. |
Afiliação: |
Mirela Angelita Artner, PIPE - UFPR; Pedro Henrique Gonzalez de Cademartori, UFPR; Francisco Avelino, Instituto Federal de Educação, Ciência e Tecnologia do Ceará; Diego Lomonaco, Universidade Federal do Ceará; WASHINGTON LUIZ ESTEVES MAGALHAES, CNPF. |
Título: |
A novel design for nanocellulose reinforced urea-formaldehyde resin: a breakthrough in amino resin synthesis and biocomposite manufacturing. |
Ano de publicação: |
2021 |
Fonte/Imprenta: |
Cellulose, v. 28, n. 6, p. 3435–3450, Apr. 2021. |
DOI: |
https://doi.org/10.1007/s10570-021-03739-4 |
Idioma: |
Inglês |
Conteúdo: |
Urea?formaldehyde (UF) resins are often reinforced with natural fibers or nanostructures such as cellulose microfibrils (CMFs) to improve their mechanical and physical properties in wood panels. However, the high-water content in these suspensions is a limitation on applications in thermosetting resins. The innovative technology investigated here consists of the in-situ production of a methanediol-based suspension of CMFs through a mechanical process and its incorporation during resin synthesis. We sought to maintain the physicochemical properties and the basic chemical composition of the resin. The synergy between the resin and CMFs provided a shielding effect and a greater storage modulus (E?). We demonstrate that this approach is robust through standard viscoelastic, physical, and mechanical tests. Likewise, a methanediol-based CMF suspension used to synthesize UF resin was effective to reduce formaldehyde emission during the resin cure reactions. Finally, the bio-based composites manufactured with this UF resin containing CMF had better performance due to increased internal bond strength by up to 15%, reduced water absorption by up to 8%, and reduced formaldehyde emission by 30% at environmental temperature. |
Palavras-Chave: |
Celulose microfibrilada; Microfibrillated cellulose; Nanocellulose; Nanocelulose; Urea formaldehyde resin; Ureia formaldeído; Wood panels. |
Thesagro: |
Painel de Madeira; Resina. |
Categoria do assunto: |
X Pesquisa, Tecnologia e Engenharia |
Marc: |
LEADER 02168naa a2200289 a 4500 001 2130463 005 2021-04-12 008 2021 bl uuuu u00u1 u #d 024 7 $ahttps://doi.org/10.1007/s10570-021-03739-4$2DOI 100 1 $aARTNER, M. A. 245 $aA novel design for nanocellulose reinforced urea-formaldehyde resin$ba breakthrough in amino resin synthesis and biocomposite manufacturing.$h[electronic resource] 260 $c2021 520 $aUrea?formaldehyde (UF) resins are often reinforced with natural fibers or nanostructures such as cellulose microfibrils (CMFs) to improve their mechanical and physical properties in wood panels. However, the high-water content in these suspensions is a limitation on applications in thermosetting resins. The innovative technology investigated here consists of the in-situ production of a methanediol-based suspension of CMFs through a mechanical process and its incorporation during resin synthesis. We sought to maintain the physicochemical properties and the basic chemical composition of the resin. The synergy between the resin and CMFs provided a shielding effect and a greater storage modulus (E?). We demonstrate that this approach is robust through standard viscoelastic, physical, and mechanical tests. Likewise, a methanediol-based CMF suspension used to synthesize UF resin was effective to reduce formaldehyde emission during the resin cure reactions. Finally, the bio-based composites manufactured with this UF resin containing CMF had better performance due to increased internal bond strength by up to 15%, reduced water absorption by up to 8%, and reduced formaldehyde emission by 30% at environmental temperature. 650 $aPainel de Madeira 650 $aResina 653 $aCelulose microfibrilada 653 $aMicrofibrillated cellulose 653 $aNanocellulose 653 $aNanocelulose 653 $aUrea formaldehyde resin 653 $aUreia formaldeído 653 $aWood panels 700 1 $aCADEMARTORI, P. H. G. de 700 1 $aAVELINO, F. 700 1 $aLEMONACO, D. 700 1 $aMAGALHAES, W. L. E. 773 $tCellulose$gv. 28, n. 6, p. 3435–3450, Apr. 2021.
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Registros recuperados : 15 | |
6. | | MATOS, M.; CLARO, F. C.; LIMA, T. A. M.; AVELINO, F.; HANSEL, F. A.; MACIEL, G. M.; LOMONACO, D.; MAGALHAES, W. L. E. Acetone: water fractionation of pyrolytic lignin improves its antioxidant and antibacterial activity. Journal of Analytical and Applied Pyrolysis, v. 156, 105175, 2021.Tipo: Artigo em Periódico Indexado | Circulação/Nível: A - 1 |
Biblioteca(s): Embrapa Florestas. |
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7. | | CLARO, F. C.; LIMA, G. G. de; LIMA, T. A. M. de; HANSEL, F. A.; MATOS, M.; AVELINO, F.; OLIVEIRA, D. R.; LOMONACO, D.; MAGALHAES, W. L. E. Characterisation of laccase-mediated lignin polymerisation: implications for molecular weight, thermal stability, and electrical properties. Biomass Conversion and Biorefinery, 2023. First online.Tipo: Artigo em Periódico Indexado | Circulação/Nível: A - 4 |
Biblioteca(s): Embrapa Florestas. |
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8. | | AVELINO, F.; MIRANDA, I. P.; MOREIRA, T. D.; BECKER, H.; ROMERO, F. B.; TANIGUCHI, C. A. K.; MAZZETTO, S. E.; SOUZA FILHO, M. de S. M. de. The influence of the structural features of lignin-based polyurethane coatings on ammonium sulfate release: kinetics and thermodynamics of the process. Journal of Coatings Technology and Research, v. 16, n. 2, p. 449-463, 2019.Tipo: Artigo em Periódico Indexado | Circulação/Nível: A - 2 |
Biblioteca(s): Embrapa Agroindústria Tropical. |
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Biblioteca(s): Embrapa Agroindústria Tropical. |
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10. | | AVELINO, F.; ALMEIDA, S. L.; DUARTE, E. B.; SOUSA, J. R.; MAZZETTO, S. E.; SOUZA FILHO, M. de S. M. de. Thermal and mechanical properties of coconut shell lignin-based polyurethanes synthesized by solvent-free polymerization. Journal of Materials Science, v. 53, n. 2, p. 1470-1486, 2018.Tipo: Artigo em Periódico Indexado | Circulação/Nível: A - 1 |
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11. | | THÁ, E. L.; MATOS, M.; AVELINO, F.; LOMONACO, D.; RODRIGUES-SOUZA, I.; GAGOSIAN, V. S. C.; CESTARI, M. M.; MAGALHAES, W. L. E.; LEME, D. M. Safety aspects of kraft lignin fractions: discussions on the in chemico antioxidant activity and the induction of oxidative stress on a cell-based in vitro model. International Journal of Biological Macromolecules, v. 182, p. 977-986, Apr. 2021.Tipo: Artigo em Periódico Indexado | Circulação/Nível: A - 1 |
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12. | | MONTEIRO, V. A. C.; SILVA, K. T. da; SILVA, L. R. R. da; MATTOS, A. L. A.; FREITAS, R. M. de; MAZZETTO, S. E.; LOMONACO, D.; AVELINO, F. Selective acid precipitation of Kraft lignin: a tool for tailored biobased additives for enhancing PVA films properties for packaging applications. Reactive & Functional Polymers, v. 166, 104980, 2021.Tipo: Artigo em Periódico Indexado | Circulação/Nível: A - 1 |
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13. | | NASCIMENTO, R. J. M.; BEZERRA, L. C. A.; ALMEIDA, J. S.; BARROS, M. DE O.; SILVA, L. R. R.; ROSA, M. de F.; MAZZETO, S. E.; LOMONACO, D.; PEREIRA, K. R. A.; AVELINO, F. Elucidating the adsorption mechanism of Rhodamine B on mesoporous coconut coir?based biosorbents through a non?linear modeling and recycling approach. Environmental Science and Pollution Research, jan. 2022.Tipo: Artigo em Periódico Indexado | Circulação/Nível: A - 1 |
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14. | | NASCIMENTO, L. DE S.; VIEIRA, F. I. D. DA M.; HORÁCIO, V.; MARQUES, F. P.; ROSA, M. de F.; SOUZA, S. A.; FREITAS, R. M. DE; UCHOA, D. E. A.; MAZZETO, S. E.; LOMONACO, D.; AVELINO, F. Tailored organosolv banana peels lignins: improved thermal, antioxidant and antimicrobial performances by controlling process parameters. International Journal of Biological Macromolecules, v. 181, p. 214-252, 2021.Tipo: Artigo em Periódico Indexado | Circulação/Nível: A - 1 |
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15. | | NASCIMENTO, L. DE S.; NASCIMENTO, R. J. M.; MATA, A. K. A. DA; FELIPE, V. T. A.; ARAÚJO, R. F.; BEZERRA, L. C. A.; ALMEIDA, J. S.; MATTOS, A. L. A.; UCHOA, D. E. A.; NOVAIS, L. M. R. DE; MONTES D’OCA, C. DA R.; AVELINO, F. Development of a phosphorous-based biorefinery process for producing lignocellulosic functional materials from coconut wastes. International Journal of Biological Macromolecules, 239, 124300, 2023.Tipo: Artigo em Periódico Indexado | Circulação/Nível: A - 1 |
Biblioteca(s): Embrapa Agroindústria Tropical. |
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Registros recuperados : 15 | |
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