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 | Acesso ao texto completo restrito à biblioteca da Embrapa Meio Ambiente. Para informações adicionais entre em contato com cnpma.biblioteca@embrapa.br. |
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Registro Completo |
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Biblioteca(s): |
Embrapa Meio Ambiente. |
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Data corrente: |
28/11/2022 |
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Data da última atualização: |
28/11/2022 |
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Tipo da produção científica: |
Artigo em Periódico Indexado |
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Autoria: |
BARIZON, R. R. M.; KUMMROW, F.; ALBUQUERQUE, A. F.; ASSALIN, M. R.; ROSA, M. A.; SOUZA, D. R. C. de; PAZIANOTTO, R. A. A. |
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Afiliação: |
ROBSON ROLLAND MONTICELLI BARIZON, CNPMA; FÁBIO KUMMROW, UNIVERSIDADE FEDERAL DE SÃO PAULO; ANJAINA FERNANDES DE ALBUQUERQUE, UNIVERSIDADE ESTADUAL DE CAMPINAS; MARCIA REGINA ASSALIN, CNPMA; MARIA APARECIDA ROSA, CNPMA; DEBORA RENATA CASSOLI DE S DUTRA, CNPMA; RICARDO ANTONIO ALMEIDA PAZIANOTTO, CNPMA. |
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Título: |
Surface water contamination from pesticide mixtures and risks to aquatic life in a high-input agricultural region of Brazil. |
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Ano de publicação: |
2022 |
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Fonte/Imprenta: |
Chemosphere, v. 308, pt. 3, article 136400, 2022. |
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Páginas: |
p. 1-10. |
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DOI: |
https://doi.org/10.1016/j.chemosphere.2022.136400 |
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Idioma: |
Inglês |
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Conteúdo: |
Abstract: The environmental risks of pesticides found in surface waters of an important agricultural basin in Brazil were estimated by adopting two approaches: individual pesticides risk quotients (RQ) and concentration addition model for pesticide mixtures (RQs) contained in each water sample. Monitoring was carried out in the Mogi Guaçu River basin, Brazil, from October 2017 to May 2018. Four sampling points were selected in the Mogi Guaçu River and seven in its tributaries A multiresidue method with solid-phase extraction and subsequent analysis by UPLC-ESI-QqQ-MS/MS was developed to quantify 19 pesticides. Herbicides, except for simazine, presented the highest detection frequencies with values above 70%. Tebuthiuron was found in all 55 analyzed samples, presenting the highest concentration (6437 ng L-1) over the monitoring period. Fungicides and insecticides showed similar detection frequency (DF) values, ranging from 1.8% to 21.8%. Tebuconazole and carbofuran were the fungicides and insecticides most frequently detected, respectively. January 2018 sampling showed the highest total concentration of pesticides, differing from March 2018 and May 2018 (p < 0.05). The MG2 > TMG8 > MG1 > TMG6 sites showed the highest concentration total of pesticides while MG4 > TMG4 > TMG3 (p < 0.05) sites showed the lowest values: MG4 > TMG4 > TMG3 (p < 0.05). Most pesticide occurrences presented no risks to aquatic organisms. Only 19 out of the 175 pesticide occurrences > LOQ presented individual risks to aquatic biota. Contrary to the results obtained by the individual risk assessment, most pesticide mixtures presented risks to aquatic biota. In 36 out of the 55 samples analyzed during monitoring, pesticide mixtures presented risks to aquatic life. MenosAbstract: The environmental risks of pesticides found in surface waters of an important agricultural basin in Brazil were estimated by adopting two approaches: individual pesticides risk quotients (RQ) and concentration addition model for pesticide mixtures (RQs) contained in each water sample. Monitoring was carried out in the Mogi Guaçu River basin, Brazil, from October 2017 to May 2018. Four sampling points were selected in the Mogi Guaçu River and seven in its tributaries A multiresidue method with solid-phase extraction and subsequent analysis by UPLC-ESI-QqQ-MS/MS was developed to quantify 19 pesticides. Herbicides, except for simazine, presented the highest detection frequencies with values above 70%. Tebuthiuron was found in all 55 analyzed samples, presenting the highest concentration (6437 ng L-1) over the monitoring period. Fungicides and insecticides showed similar detection frequency (DF) values, ranging from 1.8% to 21.8%. Tebuconazole and carbofuran were the fungicides and insecticides most frequently detected, respectively. January 2018 sampling showed the highest total concentration of pesticides, differing from March 2018 and May 2018 (p < 0.05). The MG2 > TMG8 > MG1 > TMG6 sites showed the highest concentration total of pesticides while MG4 > TMG4 > TMG3 (p < 0.05) sites showed the lowest values: MG4 > TMG4 > TMG3 (p < 0.05). Most pesticide occurrences presented no risks to aquatic organisms. Only 19 out of the 175 pesticide occurrences > LOQ presented ind... Mostrar Tudo |
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Palavras-Chave: |
Aquatic life; Multiple exposure. |
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Thesagro: |
Agrotóxico; Águas Superficiais; Análise de Risco; Fungicida; Herbicida; Poluição da Água; Resíduo Quimico. |
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Thesaurus Nal: |
Agrochemicals; Pesticide mixtures; Pesticide residues; Pesticides; Risk assessment; Water pollution. |
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Categoria do assunto: |
P Recursos Naturais, Ciências Ambientais e da Terra |
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Marc: |
LEADER 02975naa a2200397 a 4500
001 2148843
005 2022-11-28
008 2022 bl uuuu u00u1 u #d
024 7 $ahttps://doi.org/10.1016/j.chemosphere.2022.136400$2DOI
100 1 $aBARIZON, R. R. M.
245 $aSurface water contamination from pesticide mixtures and risks to aquatic life in a high-input agricultural region of Brazil.$h[electronic resource]
260 $c2022
300 $ap. 1-10.
520 $aAbstract: The environmental risks of pesticides found in surface waters of an important agricultural basin in Brazil were estimated by adopting two approaches: individual pesticides risk quotients (RQ) and concentration addition model for pesticide mixtures (RQs) contained in each water sample. Monitoring was carried out in the Mogi Guaçu River basin, Brazil, from October 2017 to May 2018. Four sampling points were selected in the Mogi Guaçu River and seven in its tributaries A multiresidue method with solid-phase extraction and subsequent analysis by UPLC-ESI-QqQ-MS/MS was developed to quantify 19 pesticides. Herbicides, except for simazine, presented the highest detection frequencies with values above 70%. Tebuthiuron was found in all 55 analyzed samples, presenting the highest concentration (6437 ng L-1) over the monitoring period. Fungicides and insecticides showed similar detection frequency (DF) values, ranging from 1.8% to 21.8%. Tebuconazole and carbofuran were the fungicides and insecticides most frequently detected, respectively. January 2018 sampling showed the highest total concentration of pesticides, differing from March 2018 and May 2018 (p < 0.05). The MG2 > TMG8 > MG1 > TMG6 sites showed the highest concentration total of pesticides while MG4 > TMG4 > TMG3 (p < 0.05) sites showed the lowest values: MG4 > TMG4 > TMG3 (p < 0.05). Most pesticide occurrences presented no risks to aquatic organisms. Only 19 out of the 175 pesticide occurrences > LOQ presented individual risks to aquatic biota. Contrary to the results obtained by the individual risk assessment, most pesticide mixtures presented risks to aquatic biota. In 36 out of the 55 samples analyzed during monitoring, pesticide mixtures presented risks to aquatic life.
650 $aAgrochemicals
650 $aPesticide mixtures
650 $aPesticide residues
650 $aPesticides
650 $aRisk assessment
650 $aWater pollution
650 $aAgrotóxico
650 $aÁguas Superficiais
650 $aAnálise de Risco
650 $aFungicida
650 $aHerbicida
650 $aPoluição da Água
650 $aResíduo Quimico
653 $aAquatic life
653 $aMultiple exposure
700 1 $aKUMMROW, F.
700 1 $aALBUQUERQUE, A. F.
700 1 $aASSALIN, M. R.
700 1 $aROSA, M. A.
700 1 $aSOUZA, D. R. C. de
700 1 $aPAZIANOTTO, R. A. A.
773 $tChemosphere$gv. 308, pt. 3, article 136400, 2022.
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Registro original: |
Embrapa Meio Ambiente (CNPMA) |
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| Registros recuperados : 60 | |
| 41. |  | NUNES, K. S. D.; VALLIM, J. H.; ASSALIN, M. R.; QUEIROZ, S. C. do N. de; PARAIBA, L. C.; JONSSON, C. M.; REYES, F. G. R. Residue depletion study, withdrawal period calculation and bioaccumulation of sulfamethazine in tilapia (Oreochromis niloticus) treated with medicated feed. Journal of Veterinary Pharmacology and Therapeutics, v. 41, n. 1, june 2018. Special Issue of the abstracts 14th International Congress of the European Association for Veterinary Pharmacology and Toxicology, June 24-27 June 2018, held a Wroclaw, Poland. Ref. P9.13. p. 123.| Tipo: Resumo em Anais de Congresso |
| Biblioteca(s): Embrapa Meio Ambiente. |
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| 42. | | ASSALIN, M. R.; FERRACINI, V. L.; QUEIROZ, S. C. do N. de; JONSSON, C. M.; CLEMENTE, Z.; SILVA, S. R. C. M. da. Photocatalytic degradation of an organophosphorus pesticide from agricultural waste by immobilized TiO2 under solar radiation. Revista Ambiente & Água, Taubaté, v. 1, n. 4, p. 778-787, 2016.| Tipo: Artigo em Periódico Indexado | Circulação/Nível: A - 2 |
| Biblioteca(s): Embrapa Meio Ambiente. |
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| 45. | | MELO, I. S. de; SOUZA, W. R.; SILVA, L. da; SANTOS, S. N.; ASSALIN, M. R.; ZUCCHI, T. D.; QUEIROZ, S. C. do N. de. Isolation and characterization of a novel Pseudomonas sp. strain from Deschampsia antarctica as a potential biocontrol agent. In: INTERNATIONAL SYMPOSIUM ON MICROBIAL ECOLOGY, 15., 2014, Seoul. Proceedings... Wageningen: The International Society for Microbial Ecology (ISME), 2014. p. 139.| Tipo: Resumo em Anais de Congresso |
| Biblioteca(s): Embrapa Meio Ambiente. |
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| 46. | | HASHIMOTO, J. C.; PASCHOAL, J. A. R.; QUEIROZ, S. C. do N. de; FERRACINI, V. L.; ASSALIN, M. R.; REYES, F. G. R. A simple method for the determination of malachite green and leucomalachite green residues in fish by a modified QuEChERS extraction and LC/MS/MS. Journal of AOAC International, Arlington, v. 95, n. 3, p. 913-922, 2012.| Tipo: Artigo em Periódico Indexado | Circulação/Nível: A - 2 |
| Biblioteca(s): Embrapa Meio Ambiente. |
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| 47. | | ASSALIN, M. R.; SOUZA, D. R. C. de; ROSA, M. A.; MOLTOCARO, R. C. R.; CASTANHA, R. F.; VILELA, E. S. D.; TASIC, L.; DURÁN, N. Thiamethoxam used as nanopesticide for the effective management of Diaphorina citri psyllid: an environmental-friendly formulation. International Journal of Pest Management, p.1-9, 2022. Online first.| Tipo: Artigo em Periódico Indexado | Circulação/Nível: A - 4 |
| Biblioteca(s): Embrapa Meio Ambiente. |
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| 48. | | BARIZON, R. R. M.; KUMMROW, F.; ALBUQUERQUE, A. F.; ASSALIN, M. R.; ROSA, M. A.; SOUZA, D. R. C. de; PAZIANOTTO, R. A. A. Surface water contamination from pesticide mixtures and risks to aquatic life in a high-input agricultural region of Brazil. Chemosphere, v. 308, pt. 3, article 136400, 2022. p. 1-10.| Tipo: Artigo em Periódico Indexado | Circulação/Nível: A - 1 |
| Biblioteca(s): Embrapa Meio Ambiente. |
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| 49. | | CLEMENTE, Z.; JONSSON, C. M.; PRESTES, E. B.; FERRACINI, V. L.; QUEIROZ, S. C. do N. de; ASSALIN, M. R.; SILVA, S. R. C. M. Toxicidade aguda de efluentes de lavagem de equipamentos agrícolas após tratamento por fotocatálise heterogênea solar. In: CONGRESSO BRASILEIRO DE TOXICOLOGIA, 17., 2011, Ribeirão Preto. Anais... Ribeirão Preto: Sociedade Brasileira de Toxicologia, 2011. Poster AM25.| Tipo: Resumo em Anais de Congresso |
| Biblioteca(s): Embrapa Meio Ambiente. |
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| 50. | | SOUZA, D. R. C. de; ASSALIN, M. R.; QUEIROZ, S. C. do N. de; FERRACINI, V. L.; ROSA, M. A.; TAVARES, M. M.; FERREIRA, G. T. Validação de metodologia para análise de alguns herbicidas em água de rio por LC-ESI-MS/MS. In: CONGRESSO LATINO-AMERICANO DE CROMATOGRAFIA E TÉCNICAS RELACIONADAS, 12., 2008, Florianóplis. Livro de resumos... Florianóplis: Instituto Internacional de Cromatografia, 2008. 1 CD-ROM| Tipo: Resumo em Anais de Congresso |
| Biblioteca(s): Embrapa Meio Ambiente. |
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| 51. | | MASCARIN, G. M.; MARINHO-PRADO, J. S.; ASSALIN, M. R.; MARTINS, L. G.; BRAGA, E. S.; TASIC, L.; DITA RODRIGUES, M. A.; LOPES, R. B. Natural occurrence of Beauveria caledonica, pathogenicity to Cosmopolites sordidus and antifungal activity against Fusarium oxysporum f. sp. cubense. Pest Management Science, v. 78, n. 11, p. 4458-4470, 2022.| Tipo: Artigo em Periódico Indexado | Circulação/Nível: A - 1 |
| Biblioteca(s): Embrapa Meio Ambiente; Embrapa Recursos Genéticos e Biotecnologia. |
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| 53. | | FAY, E. F.; CASTRO, V. L. S. S. de; SILVA, C. M. M. de S.; ABAKERLI, R. B.; ASSALIN, M. R.; EBERLIN, M. N. Metabolização do herbicida sulfentrazona: obtenção e identificação de 3-idroximetilsulfentrazona em urina de mamíferos. In: CONGRESO VIRTUAL IBEROAMERICANO SOBRE GESTIÓN DE CALIDAD EN LABORATORIOS, 4., 2007, Barcelona. Resúmenes... Barcelona: Ministerio de Agricultura, Pesca Y Alimentación, 2007. 2 p.| Tipo: Artigo em Anais de Congresso / Nota Técnica |
| Biblioteca(s): Embrapa Meio Ambiente. |
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| 54. | | MONTEIRO, R. T. R.; SILVA, G. H. da; MESSIAS, T. G.; QUEIROZ, S. C. do N. de; ASSALIN, M. R.; SOUZA, D. R. C. de; ALVES, C. H. R.; FERREIRA, A. C.; BLAISE, C. Chemical and ecotoxicological assessments of water samples before and after being processed by a water treatment plant. Revista Ambiente & Água, Taubaté, v. 9, n. 1, p. 6-18, 2014.| Tipo: Artigo em Periódico Indexado | Circulação/Nível: B - 2 |
| Biblioteca(s): Embrapa Meio Ambiente. |
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| 55. | | VALLIM, J. H.; CLEMENTE, Z.; CASTANHA, R. F.; PEREIRA, A. do E. S.; CAMPOS, E. V. R.; ASSALIN, M. R.; MAURER-MORELLI, C. V.; FRACETO, L. F.; CASTRO, V. L. S. S. de. Chitosan nanoparticles containing the insecticide dimethoate: a new approach in the reduction of harmful ecotoxicological effects. NanoImpact, v. 27, article 100408, 2022.| Tipo: Artigo em Periódico Indexado | Circulação/Nível: A - 1 |
| Biblioteca(s): Embrapa Meio Ambiente. |
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| 56. | | BAPTISTA, R. C.; FERNANDES, M. A. M.; GILAVERTE, S.; QUEIROZ, S. C. do N. de; ASSALIN, M. R.; FERRACINI, V. L.; MONTEIRO, A. L. G.; REYES, F. G. R. Determination of moxidectin in serum by liquid chromatography-tandem mass spectrometry and its application in pharmacokinetic study in lambs. Journal of the Brazilian Chemical Society, Campinas, v. 28, n. 2, p. 250-256, 2017.| Tipo: Artigo em Periódico Indexado | Circulação/Nível: A - 2 |
| Biblioteca(s): Embrapa Meio Ambiente. |
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| 57. | | ASSALIN, M. R.; SANTOS, L. D. L. dos; SOUZA, D. R. C. de; ROSA, M. A.; MOLTOCARO, R. C. R.; CASTANHA, R. F.; DONAIRE, P. P. R.; DURAN, N. Ecotoxicity evaluation: preparation of poly-e-caprolactone and chitosannanoparticles as carriers of thiamethoxam pesticide. Journal of Physics: Conference Series, v. 1323, n. 1, 2019. Edition of the Proceedings of VI NanoSAFE International Conference, Grenoble, Nov. 2018. Article 012017.| Tipo: Artigo em Periódico Indexado | Circulação/Nível: B - 1 |
| Biblioteca(s): Embrapa Meio Ambiente. |
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| 58. | | BAPTISTA, R. C.; FERNANDES, M. A. M.; GILAVERTE, S.; QUEIROZ, S. C. do N. de; FERRACINI, V. L.; ASSALIN, M. R.; MONTEIRO, A. L. G.; REYES, F. G. R. Pharmacokinetic parameters of moxidectin residue in the serum of lambs. In: ANNUAL MEETING BRAZILIAN SOCIETY OF ANIMAL SCIENCE, 50., 2013, Campinas. The integration of knowledge in animal production: abstracts. Campinas: SBZ, 2013. 1 CD ROM.| Tipo: Resumo em Anais de Congresso |
| Biblioteca(s): Embrapa Meio Ambiente. |
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| 59. | | PARAIBA, L. C.; FERREIRA, J. M. S.; FERRACINI, V. L.; RAMOS, S. R. R.; CERDEIRA, A. L.; ASSALIN, M. R.; PAZIANOTTO, R. A. A.; SANTOS, A. J. dos; PARAÍBA, C. C. M. Modeling pesticide translocation injected by endotherapy into the stem of coconut tree (Cocos nucifera L.). Spanish Journal of Agricultural Research, v. 20, n. 2, e1002, 2022.| Tipo: Artigo em Periódico Indexado | Circulação/Nível: B - 1 |
| Biblioteca(s): Embrapa Alimentos e Territórios; Embrapa Meio Ambiente. |
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| 60. | | ASSALIN, M. R.; SANTOS, L. D. L. dos; SOUZA, D. R. C. de; ROSA, M. A.; DUARTE, R. C. R. M.; CASTANHA, R. F.; DONAIRE, P. P. R.; DURAN, N. Nanoformulation as a tool for improvement of thiamethoxam encapsulation and evaluation of ecotoxicological impacts. Energy, Ecology and Environment, v. 4, n. 6. p. 310-317, 2019.| Tipo: Nota Técnica/Nota Científica |
| Biblioteca(s): Embrapa Meio Ambiente. |
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| Registros recuperados : 60 | |
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